"Is it possible without detriment to a steel or iron mold to just start pouring bullets?" YES
"I know they will come out wrinkled at first but could I do this for a few bullets on my Lyman without warping the mold?" YES
I like to preheat all my molds now, so I can open the sprue plate with a gloved hand, and NOT have to Beat on it, with a mallet...which I have done, when pouring alloy into a cold Iron mold. Also, It's nice to get good boolits after the first 1 or 2 or 3 pours...instead of 25 or 30 pours, to get the mold up to temp.